Characteristics of spin-coated metal-modified arsenic selenide films
Identifieur interne : 020780 ( Main/Repository ); précédent : 020779; suivant : 020781Characteristics of spin-coated metal-modified arsenic selenide films
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Abstract
Metal-modified amorphous arsenic selenide films were prepared by spinning a solution containing an amine salt, thioacetamide and chlorides of the impurifying metals Zn, In, Sb, Co and V on thoroughly cleaned flat glass substrates. X-ray analyses show excess total metal components for the V- and Co-modified films whilst the In-, Zn- and Sb-doped films are selenium-rich. The electrical conductivity and optical absorption measurements reveal that only the transition metals V and Co have significant effects on the transport. A narrowing of the optical band gap as well as the conductivity activation energy is observed as the impurity concentration is increased
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Characteristics of spin-coated metal-modified arsenic selenide films</title>
<author><name sortKey="Eze, F C" uniqKey="Eze F">F. C. Eze</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Univ. Nigeria, dep. physics astronomy</s1>
<s2>Nsukka</s2>
<s3>NGA</s3>
</inist:fA14>
<country>Nigeria</country>
<wicri:noRegion>Nsukka</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Okeke, C E" uniqKey="Okeke C">C. E. Okeke</name>
</author>
</titleStmt>
<publicationStmt><idno type="inist">93-0674596</idno>
<date when="1993">1993</date>
<idno type="stanalyst">PASCAL 93-0674596 INIST</idno>
<idno type="RBID">Pascal:93-0674596</idno>
<idno type="wicri:Area/Main/Corpus">01FC73</idno>
<idno type="wicri:Area/Main/Repository">020780</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0921-4526</idno>
<title level="j" type="abbreviated">Physica, B Condens. matter</title>
<title level="j" type="main">Physica. B, Condensed matter</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Activation energy</term>
<term>Amorphous state</term>
<term>Antimony</term>
<term>Arsenic Selenides</term>
<term>Cobalt</term>
<term>Doping</term>
<term>Electrical conductivity</term>
<term>Energy gap</term>
<term>Experimental study</term>
<term>Fermi level</term>
<term>Impurity density</term>
<term>Indium</term>
<term>Inorganic compound</term>
<term>Optical absorption</term>
<term>Temperature</term>
<term>Vanadium</term>
<term>Zinc</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Conductivité électrique</term>
<term>Absorption optique</term>
<term>Etat amorphe</term>
<term>Niveau Fermi</term>
<term>Dopage</term>
<term>Bande interdite</term>
<term>Concentration impureté</term>
<term>Energie activation</term>
<term>Température</term>
<term>Composé minéral</term>
<term>Vanadium</term>
<term>Cobalt</term>
<term>Zinc</term>
<term>Indium</term>
<term>Antimoine</term>
<term>Arsenic Séléniure</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Dopage</term>
<term>Composé minéral</term>
<term>Vanadium</term>
<term>Cobalt</term>
<term>Zinc</term>
<term>Antimoine</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Metal-modified amorphous arsenic selenide films were prepared by spinning a solution containing an amine salt, thioacetamide and chlorides of the impurifying metals Zn, In, Sb, Co and V on thoroughly cleaned flat glass substrates. X-ray analyses show excess total metal components for the V- and Co-modified films whilst the In-, Zn- and Sb-doped films are selenium-rich. The electrical conductivity and optical absorption measurements reveal that only the transition metals V and Co have significant effects on the transport. A narrowing of the optical band gap as well as the conductivity activation energy is observed as the impurity concentration is increased</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0921-4526</s0>
</fA01>
<fA03 i2="1"><s0>Physica, B Condens. matter</s0>
</fA03>
<fA05><s2>190</s2>
</fA05>
<fA06><s2>2-3</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Characteristics of spin-coated metal-modified arsenic selenide films</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>EZE (F. C.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>OKEKE (C. E.)</s1>
</fA11>
<fA14 i1="01"><s1>Univ. Nigeria, dep. physics astronomy</s1>
<s2>Nsukka</s2>
<s3>NGA</s3>
</fA14>
<fA20><s1>136-144</s1>
</fA20>
<fA21><s1>1993</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>145 B</s2>
<s5>354000034971540050</s5>
</fA43>
<fA44><s0>0000</s0>
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<fA45><s0>26 ref.</s0>
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<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
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<fA64 i2="1"><s0>Physica. B, Condensed matter</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Metal-modified amorphous arsenic selenide films were prepared by spinning a solution containing an amine salt, thioacetamide and chlorides of the impurifying metals Zn, In, Sb, Co and V on thoroughly cleaned flat glass substrates. X-ray analyses show excess total metal components for the V- and Co-modified films whilst the In-, Zn- and Sb-doped films are selenium-rich. The electrical conductivity and optical absorption measurements reveal that only the transition metals V and Co have significant effects on the transport. A narrowing of the optical band gap as well as the conductivity activation energy is observed as the impurity concentration is increased</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001B11B09</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="GER"><s0>Experimentelle Untersuchung</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Estudio experimental</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Conductivité électrique</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Electrical conductivity</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="GER"><s0>Elektrische Leitfaehigkeit</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Conductividad eléctrica</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Absorption optique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Optical absorption</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="GER"><s0>Optische Absorption</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Absorción óptica</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Etat amorphe</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Amorphous state</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="GER"><s0>Amorpher Zustand</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Estado amorfo</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Niveau Fermi</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Fermi level</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Nivel Fermi</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Dopage</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Doping</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="GER"><s0>Dopen</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Doping</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Bande interdite</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Energy gap</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="GER"><s0>Energieluecke</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Banda prohibida</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Concentration impureté</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Impurity density</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Concentración impureza</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Energie activation</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Activation energy</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="GER"><s0>Aktivierungsenergie</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Energía activación</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Température</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Temperature</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="GER"><s0>Temperatur</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Temperatura</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Composé minéral</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Inorganic compound</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Compuesto inorgánico</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Vanadium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Vanadium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="GER"><s0>Vanadium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Vanadio</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Cobalt</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Cobalt</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="GER"><s0>Cobalt</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Cobalto</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Zinc</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Zinc</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="GER"><s0>Zink</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Zinc</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Indium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Indium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="GER"><s0>Indium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Indio</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Antimoine</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Antimony</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="GER"><s0>Antimon</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Antimonio</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Arsenic Séléniure</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>81</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Arsenic Selenides</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>81</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Arsénico Seleniuro</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>81</s5>
</fC03>
<fN21><s1>342</s1>
</fN21>
</pA>
</standard>
</inist>
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