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Characteristics of spin-coated metal-modified arsenic selenide films

Identifieur interne : 020780 ( Main/Repository ); précédent : 020779; suivant : 020781

Characteristics of spin-coated metal-modified arsenic selenide films

Auteurs : RBID : Pascal:93-0674596

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Abstract

Metal-modified amorphous arsenic selenide films were prepared by spinning a solution containing an amine salt, thioacetamide and chlorides of the impurifying metals Zn, In, Sb, Co and V on thoroughly cleaned flat glass substrates. X-ray analyses show excess total metal components for the V- and Co-modified films whilst the In-, Zn- and Sb-doped films are selenium-rich. The electrical conductivity and optical absorption measurements reveal that only the transition metals V and Co have significant effects on the transport. A narrowing of the optical band gap as well as the conductivity activation energy is observed as the impurity concentration is increased

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Pascal:93-0674596

Le document en format XML

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<title xml:lang="en" level="a">Characteristics of spin-coated metal-modified arsenic selenide films</title>
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<name sortKey="Eze, F C" uniqKey="Eze F">F. C. Eze</name>
<affiliation wicri:level="1">
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<s1>Univ. Nigeria, dep. physics astronomy</s1>
<s2>Nsukka</s2>
<s3>NGA</s3>
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<country>Nigeria</country>
<wicri:noRegion>Nsukka</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Okeke, C E" uniqKey="Okeke C">C. E. Okeke</name>
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<date when="1993">1993</date>
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<title level="j" type="abbreviated">Physica, B Condens. matter</title>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Activation energy</term>
<term>Amorphous state</term>
<term>Antimony</term>
<term>Arsenic Selenides</term>
<term>Cobalt</term>
<term>Doping</term>
<term>Electrical conductivity</term>
<term>Energy gap</term>
<term>Experimental study</term>
<term>Fermi level</term>
<term>Impurity density</term>
<term>Indium</term>
<term>Inorganic compound</term>
<term>Optical absorption</term>
<term>Temperature</term>
<term>Vanadium</term>
<term>Zinc</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Etude expérimentale</term>
<term>Conductivité électrique</term>
<term>Absorption optique</term>
<term>Etat amorphe</term>
<term>Niveau Fermi</term>
<term>Dopage</term>
<term>Bande interdite</term>
<term>Concentration impureté</term>
<term>Energie activation</term>
<term>Température</term>
<term>Composé minéral</term>
<term>Vanadium</term>
<term>Cobalt</term>
<term>Zinc</term>
<term>Indium</term>
<term>Antimoine</term>
<term>Arsenic Séléniure</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr">
<term>Dopage</term>
<term>Composé minéral</term>
<term>Vanadium</term>
<term>Cobalt</term>
<term>Zinc</term>
<term>Antimoine</term>
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<front>
<div type="abstract" xml:lang="en">Metal-modified amorphous arsenic selenide films were prepared by spinning a solution containing an amine salt, thioacetamide and chlorides of the impurifying metals Zn, In, Sb, Co and V on thoroughly cleaned flat glass substrates. X-ray analyses show excess total metal components for the V- and Co-modified films whilst the In-, Zn- and Sb-doped films are selenium-rich. The electrical conductivity and optical absorption measurements reveal that only the transition metals V and Co have significant effects on the transport. A narrowing of the optical band gap as well as the conductivity activation energy is observed as the impurity concentration is increased</div>
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<s0>Metal-modified amorphous arsenic selenide films were prepared by spinning a solution containing an amine salt, thioacetamide and chlorides of the impurifying metals Zn, In, Sb, Co and V on thoroughly cleaned flat glass substrates. X-ray analyses show excess total metal components for the V- and Co-modified films whilst the In-, Zn- and Sb-doped films are selenium-rich. The electrical conductivity and optical absorption measurements reveal that only the transition metals V and Co have significant effects on the transport. A narrowing of the optical band gap as well as the conductivity activation energy is observed as the impurity concentration is increased</s0>
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<s0>Electrical conductivity</s0>
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<s5>02</s5>
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<s0>Absorption optique</s0>
<s5>03</s5>
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<fC03 i1="03" i2="X" l="ENG">
<s0>Optical absorption</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="GER">
<s0>Optische Absorption</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Absorción óptica</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Etat amorphe</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Amorphous state</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="GER">
<s0>Amorpher Zustand</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Estado amorfo</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Niveau Fermi</s0>
<s5>05</s5>
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<s0>Fermi level</s0>
<s5>05</s5>
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<s0>Nivel Fermi</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Dopage</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Doping</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="GER">
<s0>Dopen</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Doping</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Bande interdite</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Energy gap</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="GER">
<s0>Energieluecke</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Banda prohibida</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Concentration impureté</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Impurity density</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Concentración impureza</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Energie activation</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Activation energy</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="GER">
<s0>Aktivierungsenergie</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Energía activación</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Température</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Temperature</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="GER">
<s0>Temperatur</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Temperatura</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Composé minéral</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Inorganic compound</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Compuesto inorgánico</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Vanadium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Vanadium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="GER">
<s0>Vanadium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Vanadio</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Cobalt</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Cobalt</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="GER">
<s0>Cobalt</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Cobalto</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Zinc</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Zinc</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="GER">
<s0>Zink</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Zinc</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Indium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Indium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="GER">
<s0>Indium</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Indio</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Antimoine</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Antimony</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="GER">
<s0>Antimon</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Antimonio</s0>
<s1>SEC</s1>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>20</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Arsenic Séléniure</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>81</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Arsenic Selenides</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>81</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Arsénico Seleniuro</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>81</s5>
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<fN21>
<s1>342</s1>
</fN21>
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